Abstract:
A continuous underway measurement of dissolved gases (O
2, CO
2, Ar) in oceanic waters was developed using membrane inlet mass spectrometry (MIMS, HPR-40, HIDEN, UK).After optimizing experimental conditions, including sampling device, sampleing flow rate, sampling equilibrium temperature, we can use this method to determine the O
2/Ar ratio and
pCO
2in the surface seawater.Laboratory experiments showed that the instrument yielded high signal stability and precision.The
CV of the O
2, Ar, CO
2, O
2/Ar value during 12 h continuous measurements was 1.57%, 3.75%, 2.21%, 2.61% for a same standard solution respectively.Seven standard calibration curves drawn within 10 days also showed high reproducibility with a relative standard deviation (
RSD) of 4.18% for the seven slopes of standard calibration curves.The method was employed to determine O
2/Ar ratio and
pCO
2 in the north slope of the South China Sea(19.8°N~20.8°N, 114.7°E~115°E).O
2/Ar ranged from-2.52% to 3.34% with a mean of 0.56%±1.02%, and the mean of
pCO
2 was 361.53±40.46μatm.This method can be used to measure dissolved gases (O
2, CO
2, Ar) in oceanic waters directly, fast and with high spatial and temporal resolution, which provides a new approach to the research of net community production and
pCO
2 in marginal seas of China.