利用膜进样质谱连续走航测定表层海水O2/Ar比值和pCO2

Continuous underway measurements of sea surface O2/Ar and pCO2 by membrane inlet mass spectrometry

  • 摘要: 利用HIDEN公司HPR40溶解气体质谱分析仪,通过实验探索和实际应用,建立了连续走航高频率同时测定海水中O2、Ar和CO2等多种气体的分析方法。通过选择硅树脂膜的循环水取样器、进样流量为220 mL/min、进样平衡温度低于海水2℃等实验条件,建立了船载连续走航系统,实现了利用膜进样质谱仪(MIMS)连续走航测定表层海水O2/Ar比值和pCO2。所用仪器稳定性良好,连续测定12 h大气鼓泡48 h后的海水样品获得O2、Ar和CO2的精密度分别为1.57%、3.75%和2.21%,O2/Ar的精密度为2.61%;该方法的重复性好,10 d内绘制7条CO2工作曲线斜率的相对标准偏差RSD=4.18%。应用该方法在南海北部陆坡19.8°N~20.8°N,114.7°E~115°E断面进行调查并取得了很好的效果,结果表明:该调查断面的生物氧过饱和量Δ(O2/Ar)为0.56%±1.02%,其变化范围为-2.52%至3.34%,调查断面的pCO2值为361.53±40.46μatm。该方法具有直接、快速、高时空分辨率测定多种溶解气体的优点,为认识多组分气体的高分辨时空分布格局,深入开展我国陆架边缘海生物过饱和氧、海洋群落净生产力和pCO2动力学研究提供了新方法。

     

    Abstract: A continuous underway measurement of dissolved gases (O2, CO2, Ar) in oceanic waters was developed using membrane inlet mass spectrometry (MIMS, HPR-40, HIDEN, UK).After optimizing experimental conditions, including sampling device, sampleing flow rate, sampling equilibrium temperature, we can use this method to determine the O2/Ar ratio and pCO2in the surface seawater.Laboratory experiments showed that the instrument yielded high signal stability and precision.The CV of the O2, Ar, CO2, O2/Ar value during 12 h continuous measurements was 1.57%, 3.75%, 2.21%, 2.61% for a same standard solution respectively.Seven standard calibration curves drawn within 10 days also showed high reproducibility with a relative standard deviation (RSD) of 4.18% for the seven slopes of standard calibration curves.The method was employed to determine O2/Ar ratio and pCO2 in the north slope of the South China Sea(19.8°N~20.8°N, 114.7°E~115°E).O2/Ar ranged from-2.52% to 3.34% with a mean of 0.56%±1.02%, and the mean of pCO2 was 361.53±40.46μatm.This method can be used to measure dissolved gases (O2, CO2, Ar) in oceanic waters directly, fast and with high spatial and temporal resolution, which provides a new approach to the research of net community production and pCO2 in marginal seas of China.

     

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