黄东海大气气溶胶数浓度特征及影响因素研究

Characteristics and influencing factors of atmospheric aerosol concentration over the Yellow Sea and the East China Sea

  • 摘要: 本文根据2022年4月10日至26日我国东部海域大气气溶胶及走航气象的观测数据,对黄东海海域大气气溶胶粒子数浓度的时空分布、粒径谱分布特征以及观测中发生的新粒子生成(NPF)事件进行了研究。结果表明,靠近陆地的江苏沿海地区海洋气溶胶总数浓度为150.79~313.14 个/cm3,而远离陆地的远海海域气溶胶总数浓度仅为70 个/cm3左右;数浓度谱总体呈双峰分布,靠近陆地的海区峰值更高,且温度、湿度均未与气溶胶数浓度呈线性相关性。通过计算可知,本次航测中NPF事件的生成速率(FR)为0.14~1.45 /(cm3·s),生长速率(GR)为2.84~17.00 nm/h。与陆地NPF事件对比,本次海上观测到的核模态气溶胶粒子数浓度要低1~2个数量级,但生成速率和增长速率并无较大差异,因此,核模态气溶胶数浓度及新粒子生成速率并不是新粒子增长过程的主导因素。对观测过程中的一次NPF事件进行研究发现,相对于核模态气溶胶,积聚模态气溶胶数浓度的增加具有延后性。

     

    Abstract: In this paper, a wide range of equipment such as particle size spectrometer and automatic weather station are used to measure atmospheric aerosol, atmospheric temperature and humidity during the period of April 10 to 26, 2022 in the Yellow Sea and the East China Sea. The temporal and spatial distribution of aerosol particle number concentration and particle size spectrum and the occurrence of new particle formation (NPF) events in the Yellow Sea and the East China Sea were studied. The results show that the total concentration of Marine aerosol in coastal areas of Jiangsu is 150.79-313.14/cm3 near the land, while the total concentration of Marine aerosol far away from the land is only about 70/cm3; Number concentration spectrum showed a bimodal distribution, and the peak aerosol concentration is higher in the sea area near the land, and there was no significant correlation between temperature, humidity and aerosol concentration; The NPF event formation rate (FR) was 0.14-1.45/(cm3·s), and the growth rate (GR) was about 2.84-17.00 nm/h. Compared with the results of NPF events on land, the concentration of nucleation mode aerosol particle number observed at sea is 1 to 2 orders of magnitude lower, but there is no significant difference between the generation rate and growth rate. It is concluded that the concentration of nuclear mode aerosol and the generation rate of new particles are not the dominant factors in the growth process of new particles. In the study of an NPF event during observation, it is found that compared with the nuclear mode aerosol, the increase of the number concentration of the accumulated mode aerosol is delayed.

     

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