海南老爷海表层沉积物重金属分布特征及污染评价

Distribution characteristics and pollution evaluation of heavy metals in the surface sediment of Laoyehai lagoon, Hainan province

  • 摘要: 通过2019年测定的表层沉积物中重金属(Cu、Pb、Zn、Cd、Cr、Hg、As)、环境因子(TOC、TP、TN、硫化物)和石油类污染物的含量,探讨了老爷海表层沉积物中各因子的空间分布特征、相关性及重金属的潜在生态风险。结果表明,老爷海沉积物中各因子的分布不均匀,除TP和TN为中度变异外,其他因子均为高度变异。沉积物中各因子的分布整体表现为从内湾到外湾的递减趋势,且Cu、Pb、As、硫化物、石油类均在口门附近出现高值区。各因子的空间波动顺序为石油类>Hg>TOC>Cd>Cu>硫化物>Pb>As>Zn>Cr>TN>TP。Pearson相关性分析表明,Cd、Zn、Pb、Cr、TN、石油类、TOC、硫化物、Cu具有相同的来源或途径,均来自陆源和海源输入,主要受沿岸的海水养殖、网箱养殖、城镇工农业生产的影响。硫化物与Cd和As的富集作用相关,而Hg与其他因子的相关性较低或无相关性,说明Hg的来源不同于其他因子。7种沉积物中重金属的潜在生态风险依次为Hg>Cd>Pb>As>Cu>Zn>Cr,Hg与Cd为主要潜在生态风险因子。地累积指数的污染排序为Cd>Hg>Pb>Zn>Cr>As>Cu,老爷海沉积物为轻度污染,Cd和Hg为主要污染因子。

     

    Abstract: The spatial distribution characteristics, correlation and potential ecological risk of heavy metals in the surface sediments of the Laoyehai lagoon were investigated by measuring the contents of heavy metals Cu, Pb, Zn, Cd, Cr, Hg, As, and environment factors TOC, TP, TN, sulfide and petroleum in 2019. The results showed that the distribution of each factor in the sediments of the Laoyehai lagoon was very irregular, except for TP and TN, which were moderately variable, while all other factors were highly variable. The overall sediment factors showed a decreasing trend from the inner lagoon to the outer lagoon, and Cu, Pb, As, sulfide and petroleum all had high values near the mouth area. The coefficient of variation of each factor was in the following order, Petroleum>Hg>TOC>Cd>Cu>sulfide>Pb>As>Zn>Cr>TN>TP. Pearson correlation analysis shows that Cd, Zn, Pb, Cr, TN, Petroleum, TOC, sulfide, Cu come from the same source or in the same way, input of land and sea source pollution, it was mainly influenced by marine aquaculture, net farming, urban industrial and agricultural production. sulfide was related to the enrichment of Cd and As. The correlation between Hg and other factors is low or not, indicating that the main source of Hg is different from other factors. The potential ecological risk of 7 sediment heavy metals were in the following order, Hg>Cd>Pb>As>Cu>Zn>Cr. Hg and Cd are the main potential ecological risk factors. The geological accumulation index evaluates of pollution degree in the following order, Cd>Hg>Pb>Zn>Cr>As>Cu, the sediment of the Laoyehai lagoon is lightly polluted, and Cd and Hg were the main pollution factors.

     

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