天津渤海湾近岸海域表层沉积物重金属环境质量评价及来源分析

Environmental quality assessment and source analysis of heavy metals in coastal surface sediment of Bohai Bay along Tianjin city, China

  • 摘要: 本文根据天津近岸海域14个站位的调查结果,对表层沉积物中7种重金属元素(Cu、Pb、Zn、Cd、Cr、Hg和As)的含量和分布特征进行了分析,通过潜在生态风险指数法和一致性沉积物质量标准评价了沉积物中重金属的环境质量,并采用多元统计分析的方法对重金属的来源进行了分析。研究结果显示:天津近海表层沉积物中重金属Pb、Zn、Cd、Cr和Hg的含量均符合第一类海洋沉积物质量标准,仅Cu和As在少数站位出现超标现象;从空间分布来看,重金属含量呈现中部和南部海域较高、北部海域较低的分布特征;调查海域除Hg具有中等−强潜在生态风险外,其余重金属元素均处于轻微潜在生态风险等级,多种重金属综合潜在生态风险同样处于轻微−中等等级;As和Cr在部分站位高于重金属毒性效应阈值下限但未超过阈值上限,其余重金属元素含量均低于重金属毒性效应阈值下限,表明天津近海发生沉积物重金属生物毒性危害现象的概率较低;沉积物中Cu、Pb、Zn和Cr元素可能主要来源于自然过程,而As和Cd则主要来源于人类的工农业活动。

     

    Abstract: Based on the results of 14 stations in the coastal sea of Tianjin, we analyzed the content and distribution characteristics of 7 heavy metals (Cu, Pb, Zn, Cd, Cr, Hg and As) in surface sediments, evaluated the environmental quality of heavy metals in sediments by the potential ecological risk index method and consistent sediment quality standards, and used multivariate statistical analysis to analyze the sources of heavy metals. The results showed that the contents of Pb, Zn, Cd, Cr and Hg in the surface sediments were all in accordance with the first class of marine sediment quality standards, and only Cu and As exceeded the standards at a few stations; the contents of heavy metals were higher in the central and southern waters and lower in the northern waters from the spatial distribution; except for Hg, which had a moderate to strong potential ecological risk, the other heavy metals in the surveyed waters were all in the slight grade. As and Cr were above the lower threshold for heavy metal toxicity effects at some stations but did not exceed the upper threshold, while the remaining heavy metals were below the lower threshold for heavy metal toxicity effects, indicating that the probability of sediment heavy metal toxicity hazards in Tianjin coastal sea was low. The elements Cu, Pb, Zn and Cr in the sediments were probably mainly derived from natural processes, while As and Cd were mainly derived from human industrial and agricultural activities.

     

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