秋、冬季渤海溶解N2O的分布和通量及其影响因素

Distributions and fluxes of dissolved nitrous oxide in the Bohai Sea in autumn and winter and their influencing factors

  • 摘要: 通过2019年10月和12月对渤海海域进行的调查及样品采集,分析溶解N2O的分布和影响因素,并估算其海−气交换通量。结果表明:秋季表层海水溶解N2O浓度为(8.2±0.5)nmol/L,饱和度为(97.5±4.7)%;冬季浓度为(11.0±0.8 )nmol/L,饱和度为(93.8±4.5)%。渤海表层海水溶解N2O浓度呈现明显的季节性差异,冬季浓度高于秋季,且高值区均集中在黄河口以及莱州湾附近。秋季渤海溶解N2O处于接近饱和状态,冬季则处于不饱和状态。温度、陆源淡水输入以及沉积物−水界面交换对渤海溶解N2O的分布有重要影响。2019年10月和12月黄河向渤海输入N2O的量分别约为4.2×104 mol和1.1×104 mol,是渤海N2O的重要来源,而秋、冬季渤海底层的沉积物既可能是渤海水体N2O的源,也可能是其汇。秋季和冬季渤海N2O海−气交换通量分别为(−0.3±0.7)μmol/(m2∙d)和(−1.1±1.6)μmol/(m2∙d),与其他已报道海域相比,渤海N2O的海−气交换通量较低。初步估算秋季和冬季两季节渤海从大气吸收N2O的量为4.41×10−4 Tg,是大气N2O的汇。

     

    Abstract: Distributions and air-sea fluxes of dissolved N2O in the Bohai Sea were investigated in October and December 2019. Dissolved N2O concentrations in surface waters were (8.2±0.5) nmol/L (97.5%±4.7)% saturation in autumn and (11.0±0.8) nmol/L (93.8±4.5)% saturation in winter. Generally, surface N2O concentrations in winter were higher than in autumn. High N2O concentrations were observed mainly near the Yellow River Estuary and Laizhou bay. N2O in the Bohai Sea was close to saturation in autumn and undersaturated in winter. Temperature, riverine input and sediment-water exchange are major factors affecting distributions of dissolved N2O in the Bohai Sea. The freshwater input from the Yellow River was an important source of N2O in the Bohai Sea, with fluxes of about 4.2×104 mol in October 2019 and 1.1×104 mol in December 2019. Sediment can act as either a source or a sink of water column N2O in autumn and winter. The air-sea fluxes of the Bohai Sea were about (−0.3±0.7) μmol/(m2∙d) in autumn and (−1.1±1.6) μmol/(m2∙d) in winter, and were lower than from other coastal seas of China. The Bohai Sea acted as a N2O sink of the atmosphere in autumn and winter with a total influx of 4.41×10−4 Tg.

     

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