海水中90Sr测量的国际比对研究

International comparison of 90Sr analysis in seawater

  • 摘要: 为了检验并提高海水人工放射性核素90Sr的分析水平,本研究利用二\(2-乙基己基)磷酸(HDEHP)萃取-β计数法参与2016年国际原子能机构(IAEA)组织的海水90Sr活度分析国际比对活动,测量结果与IAEA给定的参考值一致。国际比对活动证明本方法测定海水样品中90Sr的结果可靠,且具有较低的检出限(0.14 Bq/m3)。本方法是目前中华人民共和国环保部标准HJ815-2016的重要补充,同时为今后海水90Sr的国家标准的建立打下基础,以满足我国滨海核电快速发展背景下的海水90Sr分析需求。

     

    Abstract: To examine and improve the analytical method of 90Sr in seawater, we participated in the international comparison of 90Sr analysis in seawater organized by International Atomic Energy Agency(IAEA) via the method of solvent extraction with bis-2-ethylthexyl-phosphoric acid(HDEHP) in n-heptane with β counting.The result was consistent with the reference value provided by IAEA.The minimum detection activity is as low as 0.14 Bq/m3 based on the present method.This analytical method of 90Sr can be the supplemental method for the national environmental protection standard PRC HJ815-2016 and is one of candidate methods for state standard on 90Sr analysis in seawater to satisfy the demand of 90Sr analysis in seawater under the background of a rapid development of nuclear power plants along the coastline of China.

     

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